# Project 1: Developing In Situ, Real-time Sensors for Toxicants at Superfund sites, to Protect Public Health and Optimize Cleanup

> **NIH NIH P42** · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · 2021 · $162,799

## Abstract

Project 1: Project Summary/Abstract
The Superfund program is responsible for protecting public health and the environment by cleaning up the
nation's most contaminated land as well as responding to environmental emergencies. As stated in EPA's web
material, Cleanup Optimization at Superfund Sites is a recognized part of that mission, the stated goal being,
to improve remedy protectiveness, effectiveness, and cost efficiency at all phases of a cleanup process.
Sediments and soils are commonly the dominant reservoirs of toxicants at Superfund sites, but human
exposure to toxicants is not only direct; it can occur via food chains, or, commonly, via water as toxicants are
gradually released from soils and aquatic sediments. This project will focus on two important toxicants, NDMA
and PAHs, but will also provide insights and methodologies relevant to the general problem of detection,
mapping, and movement of harmful species. To protect human health and design effective and cost-effective
cleanup requires understanding what toxicants are present, how they are distributed, and by what routes they
move through the environment and enter people. Gaining this understanding is usually a slow, difficult, and
costly process, given the extent and spatial variability of toxicant distributions and the high cost and slow speed
of chemical sampling and lab analysis. There is thus a great opportunity to improve remediation protectiveness,
effectiveness, and cost efficiency by developing new and cost-effective in situ sensor technologies that can
rapidly measure both toxicant concentrations in water and their exchange rates with contaminated sediments.
These novel sensors promise to enable research with the potential to give rise to paradigm shifting
understanding of the spatiotemporal dynamics of contaminants. Project 1 is thus both highly relevant to
the Superfund mission, and directly responsive to the third mandate of SARA Section 311(a), Methods
and technologies to detect hazardous substances in the environment. Project 1 will develop and test in
situ sensors to measure the concentrations of toxicants in water, and serve as portable sensors by field
personnel, as moored long-term sentinel sensors at fixed locations, and for toxicant mapping from
operated or autonomous vehicles. Further reflecting the critical role of contaminated sediments play, Project 1
will develop in situ technology to expeditiously determine location-specific rates at which sediment-borne
toxicants are released to their surface waters (i.e., benthic fluxes). This information will help improve
estimates of human exposure and optimize remediation strategies. Strong community interaction will be
supported by field-testing of new sensors in the Mystic River Watershed, including the tributary Malden River,
currently facing severe scrutiny for its extensive sediment contamination and for its central role in
environmental justice issues in Malden and Everett, MA. This project will also create trai...

## Key facts

- **NIH application ID:** 10145681
- **Project number:** 5P42ES027707-05
- **Recipient organization:** MASSACHUSETTS INSTITUTE OF TECHNOLOGY
- **Principal Investigator:** Harold F Hemond
- **Activity code:** P42 (R01, R21, SBIR, etc.)
- **Funding institute:** NIH
- **Fiscal year:** 2021
- **Award amount:** $162,799
- **Award type:** 5
- **Project period:** 2017-09-01 → 2022-03-31

## Primary source

NIH RePORTER: https://reporter.nih.gov/project-details/10145681

## Citation

> US National Institutes of Health, RePORTER application 10145681, Project 1: Developing In Situ, Real-time Sensors for Toxicants at Superfund sites, to Protect Public Health and Optimize Cleanup (5P42ES027707-05). Retrieved via AI Analytics 2026-05-26 from https://api.ai-analytics.org/grant/nih/10145681. Licensed CC0.

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