Synthesis of Perdeuterated Monomers and Polymers to Enhance Broadband Transparency for Plastic Optics

NSF Award Search · 01002526DB NSF RESEARCH & RELATED ACTIVIT · $760,169 · view on nsf.gov ↗

Abstract

With the support of the Macromolecular, Supramolecular and Nanochemistry Program in the Division of Chemistry, Professor Jeffrey Pyun and Professor Jon Njardarson from the University of Arizona (UA) will develop and advance novel synthetic methods to prepare monomers and polymers using deuterium chemistry. Deuterium is a naturally occurring stable isotope of hydrogen, the incorporation of which into polymers has the potential to create a revolutionary class of plastic optics with vastly improved transparency across the visible (VIS) and infrared (IR) spectrum. Currently, there remains a critical need in US defense and consumer sectors (automotive and construction) for low cost, optical glass materials that are transparent across the VIS-IR spectrum. State-of-the-art systems solely rely on heavy, expensive inorganic materials and would tremendously benefit from the creation of an alternative, low cost, light-weight plastic optical material. Hence, the UA team will explore new deuteration chemistry to prepare novel molecules and polymeric materials with the highly desirable combination of high transparency across the VIS-IR spectrum, lightweight, and robust mechanical properties over a range of temperatures. The broader impacts of the project are significant as the technological impacts of this work are far reaching, benefiting US defense systems reliant on IR optical systems, along with the pharmaceutical and nuclear energy sectors that are already heavily invested in new deut

Key facts

NSF award ID
2505153
Awardee
University of Arizona (AZ)
SAM.gov UEI
ED44Y3W6P7B9
PI
Jeffrey Pyun
Primary program
01002526DB NSF RESEARCH & RELATED ACTIVIT
All programs
Estimated total
$760,169
Funds obligated
$760,169
Transaction type
Standard Grant
Period
07/01/2025 → 06/30/2028