Unveiling Atomic-restructuring of Cu-based Bimetallic Nanocatalysts for CO2RR using In-situ/operando Electrochemical Liquid Cell Electron Microscopy

NSF Award Search · 01002526DB NSF RESEARCH & RELATED ACTIVIT · $575,000 · view on nsf.gov ↗

Abstract

With the support of the Macromolecular, Supramolecular and Nanochemistry Program in the Division of Chemistry, Professor Haimei Zheng of the University of California, Berkeley is studying copper-based nanocatalysts for carbon dioxide (CO2) conversion to useful fuels and chemicals. Copper-based bimetallic nanocatalysts have gained significant attention for their potential to improve the process of CO2 transformation; however, these catalysts do not remain unchanged during reactions—their surfaces often shift away from their original structures. Understanding how and why these changes occur is essential, as they can greatly affect how well the catalyst performs and how long it remains effective. This project aims to uncover how copper-based bimetallic catalysts transform during CO2 conversion using a powerful technique called in-situ electrochemical liquid cell transmission electron microscopy (EC-TEM). This is currently the only method capable of directly observing such atomic-scale changes in real time. By watching these transformations as they happen, the research team hopes to uncover how changes in structure and chemical bonding influence catalytic performance. The knowledge gained could help scientists design better, more efficient catalysts for energy applications. Beyond its scientific goals, the project will also provide valuable training opportunities for both graduate and undergraduate students. It will help prepare the next generation of scientists and engineers whi

Key facts

NSF award ID
2505995
Awardee
University of California-Berkeley (CA)
SAM.gov UEI
GS3YEVSS12N6
PI
Haimei Zheng
Primary program
01002526DB NSF RESEARCH & RELATED ACTIVIT
All programs
NANO NON-SOLIC SCI & ENG AWD
Estimated total
$575,000
Funds obligated
$575,000
Transaction type
Standard Grant
Period
09/01/2025 → 08/31/2028