# Understanding the selectivity and mechanisms of the hydroxyl radical-mediated electrochemical methane oxidation reaction toward reduced methane pollution

> **NSF 01002627DB NSF RESEARCH & RELATED ACTIVIT** · Regents of the University of Michigan - Ann Arbor (MI) · $418,576

## Abstract

Methane is a reactive gas that can degrade air quality. Facilities such as wastewater treatment plants routinely generate methane, and its release can affect nearby communities. Current management practices often burn or flare methane. This project will study an electrochemical methane oxidation reaction (eMOR). The reaction converts methane into methanol, a liquid chemical. The research will develop advanced materials to study methane reactions. It will also identify reaction pathways and operating conditions that favor formation of useful products. The results will guide the development of future methane conversion technologies. These eMOR technologies could be integrated with industrial biotechnologies. They may also support advanced manufacturing with more efficient use of resources. The project will also link research and education through undergraduate and graduate curriculum development, student research training, and outreach to K–12 learners. These activities will help prepare the future STEM workforce. 

This project will investigate mechanisms and kinetics of eMOR using heterostructured electrocatalyst materials that target a new reactive oxygen species (ROS) mediated C–H bond activation pathway. Electroanalytical measurements, including cyclic voltammetry, chronoamperometry, and controlled electrolysis, will be combined with quantitative product analysis to determine methane conversion, liquid product selectivity, and competing oxidation reactions as functions o

## Key facts

- **NSF award ID:** 2532908
- **Awardee organization:** Regents of the University of Michigan - Ann Arbor (MI)
- **SAM.gov UEI:** GNJ7BBP73WE9
- **PI:** Joshua Jack
- **Primary program:** 01002627DB NSF RESEARCH & RELATED ACTIVIT
- **All programs:** —
- **Estimated total:** $418,576
- **Funds obligated:** $418,576
- **Transaction type:** Standard Grant
- **Period:** 09/01/2026 → 08/31/2029

## Primary source

NSF Award Search: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2532908

## Citation

> US National Science Foundation, Award 2532908, Understanding the selectivity and mechanisms of the hydroxyl radical-mediated electrochemical methane oxidation reaction toward reduced methane pollution. Retrieved via AI Analytics 2026-06-06 from https://api.ai-analytics.org/grant/nsf/2532908. Licensed CC0.

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