This Faculty Early Career Development Program (CAREER) project is to support research and education on the design science for additively manufacturable Architected structured materials (ASMs). Architected structured materials (ASMs) are the building blocks for creating multifunctional, intelligent matter with unprecedented properties for a wide range of needs in health, energy, and aerospace applications. Existing ASMs' design paradigms produce optimal designs under the assumption of a perfect, defect-free, ideal topology, whose properties are theoretically optimized. However, due to the ASMs' intricate topologies and manufacturing process uncertainties, defects and imperfections are inevitable in the manufactured structures, which can severely degrade the ASMs' effective properties. The project will advance the realization of manufactured-as-designed ASMs by rethinking the design representation of ASMs to address the design-for-additive manufacturing (DfAM) abstraction and AM process-induced imperfections, while understanding ASMs' architecture-process-property relations to enable the generative design of manufactured-as-designed ASMs. The resulting knowledge will: 1) accelerate the ASMs' inverse design and facilitate the on-demand functional device design automation; 2) advance AM processes innovation by elucidating the material deposition for structure formation principles; 3) provide knowledge for generative design of next-generation responsive ASMs and intelligent devices. The education and outreach objective is to create an immersive learning environment and easily accessible design tools to increase participation in DfAM and AI in engineering design. This project will support participation of vertically integrated teams (VIT), the development of a virtual reality (VR)-assisted interactive design platform, the involvement of undergraduate researchers, and the integration of K-12 and NASA outreach activities. The aim of this research is to fundamentally unde